有机物A的相对分子质量为106,A中含碳、氢、氧三种元素的质量分数之比为42:3:8,故分子中N(C)=
=7,N(H)=
=6,故N(O)=
=1,故A的分子式为C
7H
6O,不饱和度为
=5,结合G的结构可知,A含有苯环,故还含有-CHO,故A的结构简式为
![](https://video.ask-data.xyz/img.php?b=https://iknow-pic.cdn.bcebos.com/d8f9d72a6059252d1912a9b5379b033b5bb5b97e?x-bce-process=image%2Fresize%2Cm_lfit%2Cw_600%2Ch_800%2Climit_1%2Fquality%2Cq_85%2Fformat%2Cf_auto)
;A被催化氧化生成C,故C为
![](https://video.ask-data.xyz/img.php?b=https://iknow-pic.cdn.bcebos.com/7dd98d1001e93901d924398f78ec54e736d19659?x-bce-process=image%2Fresize%2Cm_lfit%2Cw_600%2Ch_800%2Climit_1%2Fquality%2Cq_85%2Fformat%2Cf_auto)
.A与氢气发生加成反应生成B,B为
![](https://video.ask-data.xyz/img.php?b=https://iknow-pic.cdn.bcebos.com/902397dda144ad34b0ba3336d3a20cf431ad857e?x-bce-process=image%2Fresize%2Cm_lfit%2Cw_600%2Ch_800%2Climit_1%2Fquality%2Cq_85%2Fformat%2Cf_auto)
.由E与氯气在光照条件下生成D,D在氢氧化钠水溶液、加热条件下生成B,故E为
![](https://video.ask-data.xyz/img.php?b=https://iknow-pic.cdn.bcebos.com/e4dde71190ef76c6a0f34f9a9e16fdfaaf516759?x-bce-process=image%2Fresize%2Cm_lfit%2Cw_600%2Ch_800%2Climit_1%2Fquality%2Cq_85%2Fformat%2Cf_auto)
,D为
![](https://video.ask-data.xyz/img.php?b=https://iknow-pic.cdn.bcebos.com/ae51f3deb48f8c549bf2719e39292df5e0fe7f59?x-bce-process=image%2Fresize%2Cm_lfit%2Cw_600%2Ch_800%2Climit_1%2Fquality%2Cq_85%2Fformat%2Cf_auto)
.B与C发生酯化反应生成F,F为
![](https://video.ask-data.xyz/img.php?b=https://iknow-pic.cdn.bcebos.com/3b292df5e0fe9925a92ddde137a85edf8db17159?x-bce-process=image%2Fresize%2Cm_lfit%2Cw_600%2Ch_800%2Climit_1%2Fquality%2Cq_85%2Fformat%2Cf_auto)
,
(1)由上述分析可知,A的结构简式为
![](https://video.ask-data.xyz/img.php?b=https://iknow-pic.cdn.bcebos.com/d8f9d72a6059252d1912a9b5379b033b5bb5b97e?x-bce-process=image%2Fresize%2Cm_lfit%2Cw_600%2Ch_800%2Climit_1%2Fquality%2Cq_85%2Fformat%2Cf_auto)
,含有醛基,在新制的银氨溶液中滴加A的溶液,振荡后将试管放在热水浴中温热,产生银镜,说明含有醛基,
故答案为:
![](https://video.ask-data.xyz/img.php?b=https://iknow-pic.cdn.bcebos.com/d8f9d72a6059252d1912a9b5379b033b5bb5b97e?x-bce-process=image%2Fresize%2Cm_lfit%2Cw_600%2Ch_800%2Climit_1%2Fquality%2Cq_85%2Fformat%2Cf_auto)
;在新制的银氨溶液中滴加A的溶液,振荡后将试管放在热水浴中温热,产生银镜;
(2)A.由H的结构可知,H的分子式为C
10H
15NO,故A正确;
B.由H的结合可知,分子中含有9种化学环境不同的H原子,故物质的核磁共振氢谱图中有9组峰,故B正确;
C.由结构可知,H中除含有C、H元素外还含有O、N元素,所以不属于芳香烃,属于芳香族化合物,故C错误;
D.由结构可知,H中含有苯环,能发生加成反应,含有醇羟基,且与相接相连的碳原子相邻的碳原子上含有氧原子,可以发生消去反应,能发生氧化反应,故D正确;
故答案为:ABD;
(3)D→B是
![](https://video.ask-data.xyz/img.php?b=https://iknow-pic.cdn.bcebos.com/ae51f3deb48f8c549bf2719e39292df5e0fe7f59?x-bce-process=image%2Fresize%2Cm_lfit%2Cw_600%2Ch_800%2Climit_1%2Fquality%2Cq_85%2Fformat%2Cf_auto)
在氢氧化钠水溶液、加热条件下生成
![](https://video.ask-data.xyz/img.php?b=https://iknow-pic.cdn.bcebos.com/902397dda144ad34b0ba3336d3a20cf431ad857e?x-bce-process=image%2Fresize%2Cm_lfit%2Cw_600%2Ch_800%2Climit_1%2Fquality%2Cq_85%2Fformat%2Cf_auto)
,反应方程式为:
![](https://video.ask-data.xyz/img.php?b=https://iknow-pic.cdn.bcebos.com/35a85edf8db1cb13526d88a2de54564e92584b7e?x-bce-process=image%2Fresize%2Cm_lfit%2Cw_600%2Ch_800%2Climit_1%2Fquality%2Cq_85%2Fformat%2Cf_auto)
,
故答案为:
![](https://video.ask-data.xyz/img.php?b=https://iknow-pic.cdn.bcebos.com/35a85edf8db1cb13526d88a2de54564e92584b7e?x-bce-process=image%2Fresize%2Cm_lfit%2Cw_600%2Ch_800%2Climit_1%2Fquality%2Cq_85%2Fformat%2Cf_auto)
;
(4)反应①~⑤中属于取代反应是①②⑤,故答案为:①②⑤;
(5)B和C生成F的化学方程式为:
![](https://video.ask-data.xyz/img.php?b=https://iknow-pic.cdn.bcebos.com/7dd98d1001e93901d924398f78ec54e736d19659?x-bce-process=image%2Fresize%2Cm_lfit%2Cw_600%2Ch_800%2Climit_1%2Fquality%2Cq_85%2Fformat%2Cf_auto)
+
![](https://video.ask-data.xyz/img.php?b=https://iknow-pic.cdn.bcebos.com/902397dda144ad34b0ba3336d3a20cf431ad857e?x-bce-process=image%2Fresize%2Cm_lfit%2Cw_600%2Ch_800%2Climit_1%2Fquality%2Cq_85%2Fformat%2Cf_auto)
![](https://video.ask-data.xyz/img.php?b=https://iknow-pic.cdn.bcebos.com/3b292df5e0fe9925a92ddde137a85edf8db17159?x-bce-process=image%2Fresize%2Cm_lfit%2Cw_600%2Ch_800%2Climit_1%2Fquality%2Cq_85%2Fformat%2Cf_auto)
+H
2O,
故答案为:
![](https://video.ask-data.xyz/img.php?b=https://iknow-pic.cdn.bcebos.com/7dd98d1001e93901d924398f78ec54e736d19659?x-bce-process=image%2Fresize%2Cm_lfit%2Cw_600%2Ch_800%2Climit_1%2Fquality%2Cq_85%2Fformat%2Cf_auto)
+
![](https://video.ask-data.xyz/img.php?b=https://iknow-pic.cdn.bcebos.com/902397dda144ad34b0ba3336d3a20cf431ad857e?x-bce-process=image%2Fresize%2Cm_lfit%2Cw_600%2Ch_800%2Climit_1%2Fquality%2Cq_85%2Fformat%2Cf_auto)
![](https://video.ask-data.xyz/img.php?b=https://iknow-pic.cdn.bcebos.com/3b292df5e0fe9925a92ddde137a85edf8db17159?x-bce-process=image%2Fresize%2Cm_lfit%2Cw_600%2Ch_800%2Climit_1%2Fquality%2Cq_85%2Fformat%2Cf_auto)
+H
2O;
(6)与中间产物
![](https://video.ask-data.xyz/img.php?b=https://iknow-pic.cdn.bcebos.com/314e251f95cad1c839cdd1a57c3e6709c93d5139?x-bce-process=image%2Fresize%2Cm_lfit%2Cw_600%2Ch_800%2Climit_1%2Fquality%2Cq_85%2Fformat%2Cf_auto)
互为同分异构体,能发生消去反应,又能发生酯化反应,能发生银镜反应,故含有-OH、-CHO,且苯环上的一氯取代物只有两种,考虑为不同取代基处于对位,分子结构中没有甲基,符合结构的同分异构体为
![](https://video.ask-data.xyz/img.php?b=https://iknow-pic.cdn.bcebos.com/7dd98d1001e93901401ea0bc78ec54e736d19617?x-bce-process=image%2Fresize%2Cm_lfit%2Cw_600%2Ch_800%2Climit_1%2Fquality%2Cq_85%2Fformat%2Cf_auto)
,
故答案为:
![](https://video.ask-data.xyz/img.php?b=https://iknow-pic.cdn.bcebos.com/7dd98d1001e93901401ea0bc78ec54e736d19617?x-bce-process=image%2Fresize%2Cm_lfit%2Cw_600%2Ch_800%2Climit_1%2Fquality%2Cq_85%2Fformat%2Cf_auto)
.